Vicente Luque was a competitor for the Blackzilians on The Ultimate Fighter season 21, American Top Team vs. Blackzilians. Continuing the Blackzilians' dominance in the competition, Luque defeated the heavily favored Nathan Coy in the show's seventh bout. Luque sunk in an anaconda choke, submitting Coy in the sudden victory round of the fight. Despite the Blackzilians leading for the majority of the season, ATT made a comeback and by episode 11, the teams were tied. In an effort to earn the final upper-hand before the finale, Blackzilians selected Luque to earn their victory. Matched up against ATT's Hayder Hassan, who already won two bouts in the competition, Luque lost a split decision.
The Ultimate Fighter: American Top Team vs. Blackzilians
Episode 7 Luque def. Nathan Coy by Submission (anaconda choke) in Round 3
Episode 12 Hayder Hassan def. Luque by Split Decision